Uma Revisão Sistemática sobre Interações de Halogênio em Derivados de Nitrobenzeno Substituídos

Ricardo R.  Ternavisk; Gerardo A.  Hernández; Jean M. F. Custódio; Ademir J.  Camargo; Hamilton B. Napolitano

doi:10.19142/rpq.v13i25.493

Ricardo R. Ternavisk Unidade Universitária de Ciências Exatas e Tecnológicas, UEG
Gerardo A. Hernández Instituto Tecnológico de Tijuana, Apdo.
Jean M. F. Custódio Universidade Federal de Goiás – UFG, Goiânia, GO
Ademir J. Camargo Unidade Universitária de Ciências Exatas e Tecnológicas, UEG
Hamilton B. Napolitano Unidade Universitária de Ciências Exatas e Tecnológicas, UEG/ Centro Universitário de Anápolis – UniEVANGÉLICA

DOI: https://doi.org/10.19142/rpq.v13i25.493

Keywords: Halogen bonding, DFT, nitrobenzene

Abstract

This work aimed to analyze the halogen interactions observed in the 2,6-dibromonitrobenzene derivatives found in the literature. The searches were conducted in databases: Google Academic, Springer, PubMed and Science Direct. We identified 102 papers in the initial search of which only 11 were selected after the application of the inclusion and exclusion criteria and the reading of the papers. Based on the selected papers, only geometric parameters are considered for the investigation of halogen interactions, about 7 papers. From these data, we infer the demand for a more detailed analysis from the theoretical point of view of the interactions involving halogen atoms for this class of compounds. Especially considering the interactions between two atoms of the same species.

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